My offices often ask me, “What is the difference between carbamide peroxide and hydrogen peroxide, and which one works better for teeth whitening or tooth bleaching?” I've found that the Whiter Image products are unique becuse they add Carbamide Peroxide to Hydrogen Peroxide in most of their products, to give your patients the added benefits of both fast whitening action and anti-sensitivity.
Carbamide
peroxide
(CH6N2O3), also called urea peroxide, urea
hydrogen peroxide (UHP), and percarbamide, is an adduct of
hydrogen peroxide and urea.
Carbamide
peroxide
is mainly used as a disinfecting and bleaching agent in cosmetics and
pharmaceuticals. As a drug, this compound is used in some preparations for the
whitening of the teeth.
In
tooth bleaching, the hydrogen peroxide produced acts to oxidise extrinsic staining within tooth enamel. There are several
methods of applying the peroxide gel to the tooth ranging from night-guard
application at home or in-office application. The bleaching obtained is
proportional to the length of time the peroxide is applied to the tooth, and
the concentration used. Concentrations used for tooth whitening purposes range
between 10% and 36%. Higher concentrations may carry a higher risk of side effects
such as chemical burns of the gingiva and lips.
The
actual teeth bleaching procedure is still accomplished by placing a
peroxide-based (either hydrogen or carbamide) bleaching gel, via various
methods, into direct contact with the teeth. This contact of bleach to teeth
is made either by painting the gel directly onto the teeth or using the custom
tray method. It has been shown that these two techniques will result in
noticeable whitening of the teeth. The finished degree of whitening
ultimately achieved is predicated on the relative type, the strength or
concentration of the peroxide-based gel that is used, as well as the amount of
time that the active gel is left in contact with the surface of the teeth.
If
the concentration is low, a longer amount of contact time against the teeth
with the active bleach is needed to achieve a satisfactory result. This meant
that for the patient a number of daily treatments were needed either in the
dental office or at the patient’s home for the teeth to become satisfactorily
white.
Making
the teeth bleaching gel concentration stronger, on the other hand, would speed
the color change, but would often lead to increasingly painful tooth
sensitivity, which was a very non-desirable result for both the patient and
practitioner.
So, industry experience has been that a good result could be obtained at home if the
patient used either a medium peroxide concentration of bleaching gel coupled
with a regimen of spacing the treatments into an hour or less per day for a
number days to a week.
When
you get your teeth whitened, the hydrogen peroxide component is what actually whitens them. Tooth
bleaching today is based upon hydrogen peroxide (HP) as the active
bleaching agent. Hydrogen peroxide is a relatively unstable molecule by itself,
and will quickly disassociate into highly reactive, strong oxidizing agents
through the formation of three types of free radicals (hydroxyl radicals,
per-hydroxyl radicals, and superoxide anions), reactive oxygen molecules, and
hydrogen peroxide anions. In all of
these free radicals, it is the highly unstable free oxygen component in each
that reacts with, oxidizes, or if you will, attacks the long-chained,
dark-colored chromophore molecules, the atoms or groups in a molecule that cause
discoloration, in the patient’s teeth enamel. This attack splits the chromophore
molecules into smaller, less colored, and more dissolvable
molecules, which results in whitening of the teeth. It doesn’t really
remove any stain, but it actually changes the nature and composition of the
stains on the teeth. The final results of the bleaching treatment depends
mostly on the concentration of the Hydrogen Peroxide available to produce the
free radicals, on the amount of time the produced radicals are in contact with
the teeth, and the ease in which the radicals can reach the chromophore
molecules
Hydrogen
Peroxide, in a gel substrate, may be applied directly to the teeth, or it
can be produced in another chemical reaction from the more stable Carbamide
Peroxide (CP) in the presence of water. Carbamide peroxide has two
portions, the Carbamide portion and the Hydrogen portion.
Even
if you are using carbamide peroxide, what actually whitens your teeth is
hydrogen peroxide. Something
that many people don’t know is that carbamide peroxide is made from
hyrdrogen peroxide. To create carbamide peroxide, a urea molecule is added to
the hydrogen peroxide molecule and the result is carbamide peroxide. Please
note that there is a 3:1 relationship between carbamide and hydrogen. For
example, 12% hydrogen peroxide is theoretically equivalent to 36% carbamide
peroxide. However, this doesn’t mean that you’ll get the same results with
36% carbamide and 12% hydrogen peroxide. Carbamide Peroxide takes more time,
but Carbamide Peroxide is much more stable than Hydrogen Peroxide and also has
a much longer shelf life.
In
order for carbamide peroxide to whiten your teeth, it must first break down
into hydrogen peroxide. The problem in using carbamide in chair-side
treatments that are 15 to 20 minutes is that it takes at least 15 minutes for
carbamide peroxide to begin to break down into hydrogen peroxide (and longer to
completely break down). Only when the carbamide peroxide has broken down
into hydrogen peroxide can it begin to whiten your teeth. So if you use
carbamide peroxide for teeth whitening during a 20-minute treatment, your
customer will only have a little hydrogen peroxide on his/her teeth for 5
minutes. That’s why most people that use carbamide peroxide are using it
for take-home whitening or to prevent sensitivity. Carbamide peroxide has
been used traditionally for patient's with difficult stains and sensitivity
such as tetracycline-stained teeth, because the patients needs a much higher
level of hydrogen peroxide but doesn't want sensitivity.
Most
teeth whitening suppliers choose to use carbamide peroxide because it causes
less gum irritation than hydrogen peroxide.
When a fast single-treatment in one-hour-or-less is not being done, and
one wants to design a take home teeth bleaching kit that is safe and very
forgiving of consumer mishandling, Carbamide Peroxide is the better choice. It
is much more stable and takes longer to react than Hydrogen Peroxide. It has a
longer shelf life since it needs to come into contact with water before it
starts to react, whereas Hydrogen Peroxide can start to react by being
over-exposed to the in-office light energy.
The
last factor involved in the Carbamide Peroxide versus Hydrogen Peroxide debate
is that of using a very bright, blue light, in the visible spectrum, to
accelerate the reaction. Does one form of peroxide or the other work better
with an accelerator light? It has been shown that using a light can aid in the
bleaching process that results in whiter teeth in less time. Also, it is also seen in the literature,
that by examining the studies of the light being used in teeth bleaching, it is
always used with hydrogen peroxide instead of carbamide peroxide. It
appears that the added light energy of visible light at 480-520 nanometers
(visible spectrum blue light) helps increase the energy of activation of the
peroxide molecule to form its free radicals. Carbamide Peroxide first has to
break down into carbamide and hydrogen peroxide, so it takes longer for the
chemical combination to become ready to accept the light’s extra energy input
to help activate or catalyze the breakdown of the Hyrdrogen Peroxide into its
bleaching-capable free radicals.
Looking for products with COMBINED hydrogen peroxide and carbamide peroxide for both strength and quick uptake of whitening and for anti-sensitivity? Check out the Whiter Image whitening line through Dental Girl (www.dgdentalgirl.com) or call or email your Dental Girl representatives at linda@dental-girl.com for more info.
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